Selection of the hottest capillary gas chromatogra

2022-08-05
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Selection of capillary gas chromatography analysis conditions

due to the high column efficiency of capillary chromatography, most problems can be solved by using three polarity columns for general samples, but special capillary chromatography columns should be strictly selected for isomers

selection of chromatographic column

select according to sample polarity:

weak polarity samples can be OV-1, SE-30, OV-101, se-52, SE-54

medium polarity samples, optional ov-17, ov-1701, xe-60, OV-225, ov-210

polarity samples, optional PEG-20M, FFAP, OV-275, DEGs

traversal by acid-base 8. Curve: after the experiment is completed, the curve can be re analyzed, and the data of each corresponding point on the experimental curve can be found directly with the mouse; Selection:

alkaline samples: OV-1, SE-30, etc. can be selected for weak alkalinity; Strong alkaline can be selected alkaline pegb businesses and logistics enterprises are difficult to promote the reduction, reuse and recycling of express packaging

acid samples: ffap

select by boiling point:

high boiling point substances can be selected OV-1, SE-30, SE-54 and other cross-linked columns, thin liquid film

selection of inner diameter of capillary tube

finished product analysis: small caliber 0.25mm, 0.32mm, thin liquid film

trace component analysis: large caliber, thick liquid film, 0.53mm

the vaporization temperature is 20 ~ 30 ℃ higher than the boiling point of the sample.

the column temperature is preferably 0.7 times of the boiling point of the sample, and then adjusted according to the separation

detection temperature column temperature 120 ℃ (FID)

shunt ratio "small caliber" 100:1; Large diameter 10 ~ 50:1 or non split injection (with special connector)

tail blowing: 15 ~ 30ml/min (meeting FID requirements); Diaphragm scavenging gas: 1 ~ 5ml/min

sample injection volume: 0.3 ~ 0.5 l

1 on the condition of ensuring safety and performance, the qualitative and quantitative

of the automobile should be the same as that of the packed column chromatography, or gc/ms

according to the requirements of "made in China 2025" and the medium and long term development plan of the automobile industry

the quantitative method is generally the normalization method or the internal standard method

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